I work for the Canadian government. It is one of the most family-friendly jobs out there.
-3 weeks vacation to start
-5 "family appointment" days
-lots of sick days (I don't remember because I rarely have to use them)
-really comprehensive health benefit package
-50 weeks parental leave (a portion of that may be used by the other parent)
-options to take a "care & nurturing leave," or set up an extended leave without pay by deducting small amounts from each paycheque and then getting the money back while away
My particular department (where I do engineering work) is even better because we have a workplace culture when working from home with little notice is perfectly allowed (I have done this multiple times to allow myself a chance to walk my son to school or meet him after), business travel is somewhat discretionary in that if your family needs you at home, they'll find someone else to go, and overtime is rarely required. Because we are unionized, the overtime is paid out at 1.5x and we can either take the money, or take time in lieu. (In this manner I actually get 4 or 5 weeks of vacation a year.

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