Are you trying to do this without his knowledge to keep money from him touching, or just don't want to have to go through the work of the divorce?Â
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I ask because a friend of DH's wife just told him that she wants to file for separation so that way she can collect child support from him, and collect from the state since she won't have his income anymore (he works and makes all the money, she's a SAHM, but they've been living apart for 6 months or so and he's been paying for all of it). I think she thinks she's going to get away with getting more money from him than she does now, which isn't possible since she currently gets it all.... Anyways, I'm assuming if you file for separation then the finances would separate also, but you don't have to go through the mess of an actual "divorce" If you're trying to do this without his knowledge and just separate the finances so that way he can't touch money you're putting aside, then that obviously won't work.
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I've never been through any of it before (separation or divorce) so I don't know the actual rules or anything, but as far as I know, people can be separated for years and have totally separate lives financially without actually ever divorcing.
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If you're looking to just hide some money away, I'd think you could open a bank acct in your name only and not allow him access to it. But if you did divorce I think that money is fair game to him so you may lose half of it depending on how things are settled.