I'm in my first week postpartum now. Just wanted to say: because my babe is doing her part to get my milk supply going, my guess is that you might be able to pump quite a bit of volume.
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If you think about it, engorgement is a common problem in the very beginning. Use that to your advantage! Pump whenever you are full and pump after your DC eats. This should keep your supply up and give you plenty to pump when at work. Plus you can build a stash.
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You may want to taste test your milk early on. I found out that I had soapy tasting milk (an excess of lipase, I believe). I was never sure if my DS minded or not, but I wound up dumping my early stash. After that I began scalding everything. So you might scald, or test first to see if your milk tastes funny/soapy after a few days. You'd hate to lose any stash you accumulate.
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Good luck! You will either get all the milk you need (and then some), or you will at least get SOME milk. And I think that some has some advantages as well. I worked and pumped and had to supplement with organic formula at 9 months, but baby nursed well when I was home. (Don't forget that part! If you keep up your supply your babe will likely nurse all night with you and in the mornings if you have time, plus all weekend as well.)
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Reduce stress all you can. Keep hydrated and keep your calories up. I had a difficult time with supply whenever I wasn't eating well.










Hope you are managing alright OP