I don't have a second child yet, but but i do watch a two year old 5 days a week. Some times if i really want to sit down and just take a min to nurse my son in peace i will fix a really quick snack before. Sometimes i will give him a toy that he enjoys but only give it to him when i need a min. You could maybe start a coloring project or something that will hold her attention. It takes a little getting used to but it will happen. Eventually you will grow another arm. I have chased him across the room several times with my son attached while trying to grab something from the little boy's hand. Sometimes sitting down on the floor with him helps him stay interested in what he is doing longer. Also, i find that putting soft music on, or turning on a fan, or the dryer, helps Kaiden go to sleep better if there is talking going on.
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Playing Simon Says quietly works sometimes. Simon says count to ten in your brain, Simon says see how quietly you can walk around this whole room, Simon says blink your eyes really fast, wiggle your fingers, breath five really slow, deep breaths....
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Be creative, they love it! :)