Here's what I strive for... this happens a couple of times per week, maybe. The rest of the time I just wing it. Life is much easier, though, when I stick to the plan.
7:00ish: we all get up
from 7-8 or 8:30 I do my personal reading, unload the dishwasher, make the bed, eat breakfast, drink coffee, tell the kids to get dressed and make their beds, feed them breakfast, check my online stuff (lots less than normal recently), start a load of laundry, say goodbye to DH (not necessarily in that order!).
8 or 8:30: "school." We do a devotion, and then something that I have planned. At 5 and 3 years old, it's nothing terribly complicated most days. A game, reading a book, and a math worksheet is more than enough, imo. We're usually done by 9:00ish.
Then I get in the shower, get dressed, pack up a lunch (if we have a playdate or park day, which is most days), do a quick pickup of the house, switch the laundry. Most days we leave the house by 10:30ish. During this time, sometimes the kids play, sometimes they watch TV, Justin sometimes plays a computer game.
Most days we're home from our playdate/activity by 2:00 or so, and the afternoon is spent playing, doing some more cleaning (this is when I'll clean the bathroom or sweep/wash the floors, vacuum, put the laundry away, etc), painting, making playdoh, or other messyish things. Now that it's hot out, we won't go outside until 5:00 or later, but during the cooler months (we live in FL) we'll spend a good chunk of time outside.
A few days per week, my niece (10 months) comes over at around 4:00 to be babysat while my SIL works. Those days I try extra hard to get all cleaning done before she comes! The days we don't have her, though, sometimes I'm vacuuming at 5 or 6:00.
While I'm making dinner, sometimes the kids will take a bath, other times they'll play, and take a bath after dinner. DH will come home between 6 and 7 most of the time, so some Daddy time gets squeezed in there too.
The kids go to bed around 8:30, and I try to go to bed around 11:00, though sometimes I'm up later.
So that's what happens about three days per week. Other days, though, I spend too much time on the computer or reading in the morning (blush), and things get put off. Those are the days that I end up popping in a video and begging the kids to please just be quiet while I scramble to get housework done in the afternoon. Or if I don't run the dishwasher before I go to bed, then it's extra work in the morning, and that tends to throw the whole day off. I'm one who would like to live by my whims, but realistically, I know my day goes much better when I stick to a routine. The kids seem to do better with a rhythm as well.
You can read about more of our days at my homeschooling
blog, if you want to. I think it's something every family needs to iron out themselves...not a one size fits all. Just like you did when your first child was a newborn, you need to adjust to the rhythm of your life and plan accordingly. Of course with kids, you never know what's going to happen, so you have to plan (or not!) for that too.
