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If you get a chance to search, there have been a few threads about this. (that is an fyi-please don't take it the wrong way)
I think the general conclusion was that emergen-c is ok for when you are sick, but sodium ascorbate is better. Also, Emergen-c has something artificial in it some people object to especially for babies (aspartame?). I would give it to my kids if that was all I had around. I do think it works.j
Also if you are not sick, the general conclusion was to use regular vitamin C if you need to supplement. I do not know much about that...I have just seen it posted here.