It will work. One layer or two, the fleecy side in or out. I do like the fleecy side for wiping up poos. Sweatshirt fleece makes excellent diapers and doublers too.
I have been given lots of old sweatshirts and t shirts and have made lots of wipes,by juts serging a double layer of them around the edges.
The bigger scraps I used as soaker layers,just check the cotton % for use in a nappy! think 80% is the minimum.
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