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Has anyone experienced skin reactions to their homemade detergents?

I recently made some using Borax, Washing Soda (A&H) and a bar of soap (Clear& Pure from Melaleuca). I haven't noticed a reaction on DH,DD1 ot myself, but DD2 seems to have a wicked case of infant acne. I'm thinking it is from the new stuff...

Any thoughts? Any similar experiences?

TIA!
 

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Our homemade detergent gave my baby terrible diaper rash. I'm not sure if it didn't get things clean enough or if it was a reaction to one of the ingredients...he had a similar reaction to laundry soaps like Charlie's too, which is basically like the homemade recipes. I had to go back to using liquid detergent.
 
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